Taking the stage in a slinky and shiny black catsuit, Hadid lip-synchs to the group's 1999 tune "Larger Than Life" while straddling a faux motorcycle.
Flanked by backup dancers in Britney Spears-esque latex red jumpsuits, Hadid inspires cheers when A.J. McLean and Nick Carter join her onstage.
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As the trio performs the climactic chorus, hosts LL Cool J and Chrissy Teigen laugh in approval.
The reality TV appearance isn't the first time the boy band and Hadid, 20, have crossed paths. The model couldn't hold back her squeals while standing front row for the group's performance at the fall 2015 Balmain x H&M event in N.Y.C.
Hadid and Posey will go mic-to-mic on Lip Sync Battle on Thursday at 10 p.m. ET on Spike.