Song: "Set Fire to the Rain (Live)"
Nominated for: Best pop solo performance
Relationship status: Cue the love songs – she has a boyfriend and a baby

A year after the sensitive singer emerged as the Brit darling of the Grammy Awards, her album 21 still has her faithful legion of lonely hearts reaching for their hankies. Singing as the jilted ex-lover in "Set Fire to the Rain," she told MTV in 2011, "[The] fact that people are taking it to their hearts is like the best way to recover."