05/29/2006 at 01:00 AM EDT
Pine, 25, is a pro at playing Prince Charming. The son of CHiPs costar Robert Pine, he romanced Anne Hathaway
in The Princess Diaries 2
and now stars with Lindsay Lohan
in Just My Luck
ON SMOOCHING LINDSAY LOHAN
She's a great kisser. At the beginning I thought, "Do you do tongue in the movies?" I didn't know so I stayed strictly PG-13.
ON LUCKING INTO ACTING In college I was a total nerd and super shy. My buddy was big in the theater department and he invited me to try it. I never had any romantic visions of acting. I've seen it when it's really good and when there's no money.
ON THE TOUGH LIFE OF A PRETTY BOY Friends tease me all the time. It's mostly for my hair. They'll say, "Your head's getting bigger!" Anything they can think of to make me feel like a schmuck. Or if I ever have a hard day, there's a lot of, "Oh, poor Chris—you had to kiss Lindsay Lohan
. You had to kiss Anne Hathaway
ON CHANGING HIS IMAGE I just played a neo-Nazi assassin [in Smokin' Aces
]. I had a shaved head and blacked-out teeth. I killed Ben Affleck
and did a ventriloquism act with his mouth. It was awesome.