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favorite Chris Daughtry has signed to guest-star on the 100th episode of CBS's CSI: NY
, PEOPLE has learned.
Also bound for the same episode are Rumer Willis
, who has already shot her appearance, and Scott Wolf.
The 100th show, set to air in November, centers on the pursuit of a serial killer who targets people named Mac Taylor – the name of the character played by the show's Gary Sinese.
Daughtry – who is slated to shoot his role on Monday – has been cast as Machiavelli Taylor, described in the production notes as "an attractive 30-something year old musician."
Willis and Wolf also play characters named Mac Taylor.
Others guest-starring in the episode are Julia Ormand, actor-rapper Nelly and NFL star Marshall Faulk.