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The singer and actress is spearheading the "Botox Cosmetic: Express Success" charitable education campaign to benefit Dress for Success, an organization that helps disadvantaged women succeed in the corporate world by providing professional attire as well as career support.
You can pledge your support now at ExpressSuccessCampaign.com – and also enter to win a trip for two to New York City to have lunch with Vanessa Williams.
Williams, whose new album The Real Thing is out now, will officially launch the campaign on June 30.
For a look at Vanessa's beautiful home, check out the latest issue of PEOPLE.
