Dave Matthews & Kenny Chesney to Duet at CMA Awards
10/19/2009 AT 08:00 AM EDT
Matthews, 42, will be making his debut appearance on the awards show, where he will perform "I'm Alive," a Top 10 country hit from Chesney's Lucky Old Sun album.
Already announced to perform on the awards show are Tim McGraw, Brad Paisley, Taylor Swift, Carrie Underwood and others.
– Eileen Finan