The matches were announced Wednesday morning on Good Morning America:
American soccer star Hope Solo will attempt to fill the dancing shoes of season 12 finalist Kirstie Alley alongside Maksim Chmerkovskiy, who hoped to dance with the goalie.
The show's first transgender contestant, Chaz Bono, will dance with Lacey Schwimmer.
Soap star and Iraqi war veteran J.R. Martinez has been paired with seasoned Dancing vet Karina Smirnoff.
HLN's Nancy Grace will face the judges with Irish dance pro Tristan MacManus.
Reality star Rob Kardashian has the honor of performing with two-time Dancing champion Cheryl Burke.
Los Angeles Laker Ron Artest, who is dancing for his cancer-survivor daughter, has Peta Murgatroyd as his partner.
"Terrified" actress Ricki Lake will hold hands with returning pro Derek Hough, who last danced away with a mirror-ball trophy with season 11 winner Jennifer Grey.
George Clooney's ex-girlfriend Elisabetta Canalis will perform with Maksim's brother Val Chmerkovskiy.
Style star Carson Kressley will dazzle on the dance floor with pro Anna Trebunskaya.
Musician Chynna Phillips will have Kate Gosselin's former partner Tony Dovolani by her side.
Actor David Arquette will be in good hands: his partner is reigning champ Kym Johnson, who took the mirror-ball trophy with Hines Ward in May.
And reality star Kristin Cavallari and two-time champ Mark Ballas will hit the ballroom together when the show returns Sept. 19 on ABC.