Alec Baldwin (left) and Russell Brand, in Rock of Ages
06/01/2012 AT 08:00 AM EDT
There was quite the bromance brewing between Russell Brand and Alec Baldwin during the filming of Rock of Ages
Brand, 36, who had nothing but wonderful things to say about the 30 Rock
star, 54, even gushed – presumably jokingly – about smooching his pal in the movie.
"I get to kiss Alec Baldwin," Sunday's MTV Movie Awards host told reporters on Thursday. "He is [a good kisser]."
Getting into the details of the lip-lock, Brand says, "It is right on the mouth. It is sexy because Alec is a sexy man."
And without hesitation, the British funnyman goes on to say, "I certainly don't regret [kissing him]. I'd do it again if there was a sequel – or even if there wasn't."
Although he didn't share the same kind of scene with Tom Cruise
, he had equal praise for him.
"You'd think if [someone] were the biggest movie star in the world, they wouldn't be so interested in other people, but he's very interested and caring," Brand told PEOPLE. "He really cares about what he does. He's a serious guy but very sweet. He's a joy to be around."
Brand, who says he doesn't rehearse for his hosting gigs before they happen, predicts he'll promote his upcoming summer film quite a bit when viewers catch him during the awards, which air Sunday, June 3, at 9 p.m./8 p.m. Central.
Rock of Ages
hits theaters June 15.