Matthew McConaughey Steps Out Wearing New Wedding Ring

UPDATED 06/12/2012 at 01:00 PM EDT Originally published 06/12/2012 at 10:50 AM EDT

Matthew McConaughey Married to Camila Alves; Steps Out with Wedding Ring
Matthew McConaughey
Breedo/Deano/Splash News Online
After a three-day affair marking his wedding to Camila Alves (now Camila McConaughey!), it was back to work for Matthew McConaughey – working out, that is.

But McConaughey, 42, who tied the knot in a sunset ceremony Saturday on the couple's sprawling Austin, Texas, property, rocked his gym attire with a very special accessory Monday: his wedding ring.

It was the first time the newlywed has been photographed since his nuptials, which guests – including their their two kids, Levi, who turns 4 next month, and daughter Vida, 2½ – celebrated throughout the weekend.

Activities ranged from lounging in hammocks and playing lawn games to sleeping in luxury tents pitched across the property for the occasion.

And his sweat-soaked attire was a little different than the look he sported Saturday during the after-dusk ceremony.

"Matthew looked so handsome – like an old Hollywood movie star," a guest told PEOPLE of McConaughey, who donned a three-piece black Dolce & Gabbana tuxedo alongside his wife, "glowing and beautiful" in a gown by a favorite Brazilian designer.

For an inside look at Matthew and Camila's wedding weekend, with photos and you-are-there details, pick up next week's issue – with a first-look on on Wednesday at 8 a.m.!
To get a sneak peek of this week’s issue click here

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