"I just said, 'Let me get some shots of the dog, because I'm a huge animal lover,'" says Hubal, who is also the online magazine's editor in chief. "She had a hat for herself that she put on the dog – she was just so cute with him."
While Osbourne got glam in a stunning Chanel gown for one shot, Sid actually put the Fashion Police host to work, too.
"She had to make sure everything was picked up off the floor because Sid will pee on it," Hubal tells PEOPLE. "She was always picking stuff up and making sure the dog wasn't near it."
To see more photos from Osbourne's Maniac Magazine shoot for the September/October issue, visit their website.
April Hubal / Maniac Magazine