• JUNE 2005  photo | Brad Pitt

Credit: Vince Bucci/Getty

Published: Wednesday September 26, 2007 15:00 PM EDT

2007

JUNE 2005

Amid his separation from Jennifer Aniston, Pitt made waves when he appeared at the Los Angeles premiere of Mr. & Mrs. Smith – and not because the buzz around Angelina Jolie. He had bleached blond locks! The new color wasn't a hit with everyone: Aniston snickered to Vanity Fair, "Billy Idol called – he wants his look back."