Most Beautiful Couples

From Jessica Simpson & Nick Lachey to Jennifer Lopez & Marc Anthony, see which 12 couples make the most attractive pairs in Hollywood. By Serena Kappes

REESE & RYAN

"It was a pretty intense, emotional connection," Ryan Phillippe, 30, has said of meeting Reese Witherspoon at her 21st birthday party in 1997. And what does Phillippe find appealing of his wife of almost five years? "Reese is a happy, lighthearted person, but she's also incredibly intelligent." Witherspoon, 29, who's balanced a successful acting career with raising kids Ava, 5, and Deacon, 1, says that she sees herself as "a mom and wife, and that's what I like to be."