PEOPLE Style Awards

Angelina, Beyonce, Jessica – style director Susan Kaufman reveals her annual list of fashion's biggest stars. By Serena Kappes

SEXIEST RED-CARPET MOMENT: ANGELINA JOLIE

Angelina Jolie turned heads when she showed up to the June 7 Hollywood premiere of Mr. & Mrs. Smith in a sultry Versace leather gown. "Who else could wear black leather head to toe and look sexy and not trashy?" says Kaufman.