Hottest Celebrity Couples

Smart, sexy and successful, see how these 22 Hollywood power duos – Brad & Angelina! Posh & Becks! – keep it sizzling. By Karen J. Quan

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Keith Urban & Nicole Kidman

The twosome – who tied the knot in 2006 – only have eyes for each other at the 2007 ARIA Awards in October. And this couple doesn't shy from grand displays of affection: At a Sept. 16 show in Vancouver, Urban dedicated a song to Kidman, professing, "I would not be here tonight playing for you guys if it wasn't for the extraordinary faith and love of my wife."