Hottest Celebrity Couples

Smart, sexy and successful, see how these 22 Hollywood power duos – Brad & Angelina! Posh & Becks! – keep it sizzling. By Karen J. Quan

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Nicole Richie & Joel Madden

They may have just welcomed daughter Harlow Winter Kate Madden into the world last month, but the new parents are already teaching their newborn a lesson in generosity. With a few of their closest bear friends, the duo held a meet-and-greet for children in need during their Richie Madden Children's Foundation Holiday Party in December.