The Gossip Girl couple step out for a charity event in New York. Plus: Oprah Winfrey, Scarlett Johansson, Orlando Bloom and more
Published: Wednesday Oct 21, 2009 | 05:00 PM EDT
More from PEOPLE
- Three Arrested, Including 17-Year-Old Girl, in Triple Homicide of California Parents and Friend
- Read the Cover Story: Brad & Angelina Split After 12 Years: It's Over
- FROM EW: Garth Brooks Earns Historic RIAA Achievement: How the Country Star Beat the Beatles
- WATCH: First Presidential Debate Is Streaming Live on PEOPLE!
- Tom Hanks Orders Clam 'Chowdah' and Leaves Generous Tip at Boston Restaurant