Ashlee Simpson & Pete Wentz: The Way They Were

From parties and premieres to business and baby, look back at the couple's rockin' romance


Seven months after a PDA-filled night in New York, Ashlee Simpson and Pete Wentz step out as a couple on April 30, 2007 to host an opening-night bash at Wentz's new Big Apple lounge, Angels & Kings. "I think the first day that we met that we were attracted to each other," Simpson tells PEOPLE. But the attraction ends four years later, when Simpson, 26, files for divorce from her longtime love, 31.