A Look Back at Brad Pitt & Angelina Jolie's Best Collaborations

From Mr. & Mrs. Smith to their advocacy for women's health, the couple accomplished quite a bit during their 12 years together, which included two years of marriage

PHILANTHROPY

While they are independently passionate about their respective humanitarian causes – she on refugee issues and he on helping post-Katrina New Orleans – together through the Jolie-Pitt Foundation, they have donated millions of dollars toward efforts as varied as the treatment of HIV/AIDS, wildlife conservation and disaster relief.