Brad Pitt & Angelina Jolie's Best Collaborations

From Mr. & Mrs. Smith to their advocacy for women's health, see the lasting contributions the couple has made together

MR. & MRS. SMITH

Nicole Kidman was originally slated to star opposite Brad Pitt in the 2005 spy action flick but dropped out, leading to one of the sexiest on-screen romances in recent Hollywood history when Angelina Jolie signed on for the part.