Weddings with the Biggest VIP Guest Lists

From Jennifer and Justin's intimate affair to George Clooney's Italian bash, see which star nuptials brought out a who's who of Hollywood

JUSTIN & JESSICA

"It was a total fantasy experience," Biel told PEOPLE of her Oct. 19, 2012, wedding to Timberlake, for which she donned a custom, petal pink Giambattista Valli Haute Couture gown to tie the knot at the Borgo Egnazia resort in southern Italy. "It was a lot to ask of them to travel, so we figured we'd give our guests a good party!" added the singer.