Check out the leading man looks that made Pierce Brosnan (above with Thomas Crown Affair co-star Rene Russo) PEOPLE'S Sexiest Man Alive 2001.
Credit: Gregg De Guire/LFI
Updated: Saturday Apr 03, 2004 | 01:00 AM EST
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Three years after accepting the Bond role, Brosnan received star number 2,099 on the Hollywood Walk of Fame on Dec. 3, 1997.
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