The Sexiest Man Alive 2001: Pierce Brosnan

Check out the leading man looks that made Pierce Brosnan (above with Thomas Crown Affair co-star Rene Russo) PEOPLE'S Sexiest Man Alive 2001.

STAR POWER

Three years after accepting the Bond role, Brosnan received star number 2,099 on the Hollywood Walk of Fame on Dec. 3, 1997.