The Sexiest Man Alive 2001: Pierce Brosnan

Check out the leading man looks that made Pierce Brosnan (above with Thomas Crown Affair co-star Rene Russo) PEOPLE'S Sexiest Man Alive 2001.

BOND, JAMES BOND

Following in the footsteps of Sean Connery and Roger Moore, Brosnan dazzled audiences – and co-star Izabella Scorupco – as the world's most dashing secret agent in 1995's Goldeneye.