The Sexiest Man Alive 2001: Pierce Brosnan

Check out the leading man looks that made Pierce Brosnan (above with Thomas Crown Affair co-star Rene Russo) PEOPLE'S Sexiest Man Alive 2001.

LADY'S MAN

Widowed in 1991 when his wife died of ovarian cancer, Brosnan found love again in 1994 after meeting environmental journalist Keely Shaye Smith during an interview in Mexico. That year, the couple attended the Carousel of Hope Benefit for the Children's Diabetes Foundation.