The Sexiest Man Alive 2001: Pierce Brosnan

Check out the leading man looks that made Pierce Brosnan (above with Thomas Crown Affair co-star Rene Russo) PEOPLE'S Sexiest Man Alive 2001.

WEDDING BELLS

Pierce Brosnan and Keely Shaye Smith announced their nuptial plans in 2000, but postponed the ceremony after Brosnan's son Sean suffered serious injuries in a car accident in April. The couple tied the knot in August 2001 in a Roman Catholic ceremony in Ireland.