Photo SpecialPEOPLE's Style Awards

BEST MATCHED COUPLE: JENNIFER ANISTON & BRAD PITT

Whatever the occasion, Aniston (wearing Atelier Versace) and Pitt (in a Neil Barrett tuxedo) always choose clothes that complement each other, says Kaufman. Pitt (next up in Ocean's Twelve) and Aniston (currently filming Otherwise Engaged with Kevin Costner) are "both just simply chic. They're classic without being boring." Simply put, their outfits "are a backdrop for them as opposed to overwhelming them."

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