2006's Most Beautiful Star: Angelina Jolie

04/26/2006 at 09:00 AM EDT

2006's Most Beautiful Star: Angelina Jolie
"The proportion of her face is beautiful," director Oliver Stone says of Jolie (in Versace at the Mr. & Mrs. Smith premiere last summer). "She's a great package, beautifully put together."
TAMMIE ARROYO/AFF
2006's Most Beautiful Star: Angelina Jolie| Angelina Jolie

Attending the 2004 Arab Children's Congress in Jordan.

ALI JAREKJI / REUTERS / Landov

Once again, Jolie – in a casual tank top and jeans – dressed for comfort, not luxury. "She looks the most beautiful when she's in the field – natural, no makeup, nothing," says Jean. "Because you see Angelina, the angel. It doesn't get any better than that."

Transitioning between no-frills aid worker and red-carpet-ready Oscar winner is effortless for Jolie, who signed a reported $12 million endorsement deal last fall with St. John with the stipulation that money will go to a charity for children's causes. Says Robert De Niro, who directed her in the upcoming drama The Good Shepherd: "She has a kind of Audrey Hepburn-ish quality about her but with her own uniqueness."

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