2006's Most Beautiful Star: Angelina Jolie

04/26/2006 at 09:00 AM EDT

2006's Most Beautiful Star: Angelina Jolie
"The proportion of her face is beautiful," director Oliver Stone says of Jolie (in Versace at the Mr. & Mrs. Smith premiere last summer). "She's a great package, beautifully put together."
TAMMIE ARROYO/AFF
2006's Most Beautiful Star: Angelina Jolie| Angelina Jolie

"Her beauty lies in her work," pal Wyclef Jean says of the actress (at a local community center in Namibia on April 23).

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Like that other beauty icon (and fellow U.N. goodwill ambassador), Jolie can't help but transfix. "There's something mesmerizing about her face," says producer Steve Starkey, who worked with her on the upcoming film Beowulf. "Her smile lights up a room and her eyes are just penetrating."

Still, it's yet another role that reveals the actress at her most breathtaking. Expecting her first child with Pitt any day, the mom-to-be "glows," says Rebecca Matthias, head of maternity-wear retailer A Pea in the Pod, where Jolie stocked up on spring cashmeres and designer denim. "She's probably more beautiful than we've ever seen her."

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