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EXCLUSIVE: Gossip Girl Season 3 Spoilers!

Chuck & Blair! Serena! PEOPLE.com gets the inside scoop on what to expect when the hit CW show returns on Sept. 14

CHUCK & BLAIR: IT'S ON!

"Chuck (Ed Westwick) and Blair (Leighton Meester) are definitely going to be a couple and stay a couple this season," Gossip Girl executive producer Stephanie Savage tells PEOPLE. But don't expect it to be all chocolates and roses: "Chuck and Blair in a relationship is going to be something very unique and something we haven't seen before. They have definitely found ways to not be boring." Now thatsounds interesting.