Forget the acting, it's all about the gowns. See who the big red-carpet winners were (Penélope! Cate!) on Hollywood's biggest night. By Melissa Liebling-Goldberg
Updated: Sunday Feb 25, 2007 | 09:00 PM EST
More from PEOPLE
See More News
Sean Penn gets a lift, Clooney makes a toast and more after the big show
17 of 20
The actress must have paid close attention on the set of The Devil Wears Prada: The presenter looks simply stunning in an inky-blue sequined Calvin Klein gown, Lana Marks clutch and H.Stern jewels.
Copyright © 2013 Time Inc. All rights reserved. Reproduction in whole or in part without permission is prohibited.
In partnership with AOL