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FIRST PHOTO: See George & Amal on Their Wedding Night!

Most Beautiful 2009

World's Most Beautiful People

From superstars like Kate, Salma and Carrie to hot newcomers (the cast of Gossip Girl!), get a peek at who's on PEOPLE's 100 Most Beautiful list!

RUMER WILLIS

"I grew up with a mom that most moms don't look like," says the star of last summer's comedy The House Bunny. But with a little help from mom Demi Moore, and some experimentation, she's finding her own way: "There's a cool Korean spa my mom found in L.A. I go with my best friend, [Gossip Girl's] Jessica Szohr. That and getting my nails done are my biggest indulgences."