Most Beautiful 2014

10 Most Beautiful Celebrity Arrivals

Whether it's a plane, a train or an automobile, these gorgeous women know how to make an entrance

ANGELINA JOLIE

The beaming bride-to-be – and PEOPLE's 2006 Most Beautiful cover girl – emerges from her Audi town car at the May 2011 Cannes Film Festival premiere of her fiancé's film, The Tree of Life.