Before Reynolds welcomed daughter James with wife Blake Lively in 2014, the actor was just your standard super-hot actor, nabbing the Sexiest Man Alive title in 2010. But in 2016, PEOPLE upgraded his title to Sexiest Dad Alive. "What?! I mean come on! I mean scientifically speaking, what's sexier than a man that fornicates, producers children and then looks surprised about it," he joked about his cover to Jimmy Fallon. The couple's second child is on the way.